Finishers Think Tank

by

Marty Borruso

26 Flagship Circle

Staten Island, NY 10309

Phone: 1/800-366-5065

Originally Published in:

PLATING AND SURFACE FINISHING

Journal of the American Electroplaters and Surface Finishers Society

April, 1993

Nuts & Bolts

It is often necessary to deposit metals over passive surfaces of either stainless steel or previously applied nickel. To accomplish this and achieve good adhesion, you must understand and use what has become known as a "Woods Nickel Strike." Personally, l like the use of such a bath over most ferrous substrates. The all-chloride formulation makes this system very effective in removing all types of scale, oxides and flash rust. When operating over a ferrous substrate with an electroless nickel process, I find the use of a Woods or modified Woods formulation indispensable. First, the system removes any flash rust from the substrate and keeps it out of the EN process and, second, the EN bath lasts longer because the impurities from the cleaning process are not brought along from the preparatory steps, with the parts. Last, because the Woods strike removes all the flash rust from the parts, l can make the cleaning and preparation steps much more severe than I would ordinarily, and produce a chemically clean surface for further processing.

A preferred formulation of an ali-chloride strike that l like to use in the field is this:

This type of process will yield an active surface of passive parts and will allow further processing with other finishes.

Typically, this solution is followed by a nickel coating. The deposit from an all-chloride bath, at very low pH, is fine-grained and smooth, but inherently very stressed, so that the thickness of deposit derived from the Woods Nickel step should be very low. The success of plating over passive surfaces depends greatly on both the condition of the Woods Nickel Strike and the overall preparation cycle. This is not to say that this is the only process that will work, but to improve the success of such a process, I have used this cycle with consistent results. A modification of this process might be more dependable over some substrates: