Coating
Technology For Advanced Applications
Not
to be confused with conventional plating, these coatings are engineered
for superior protection
By
Beverly A. Graves, Editor
bgraves@pfonline.com
The
finishing industry is familiar with generic hard chromium, thin-dense
chromium, titanium nitriding, electroless nickel and various nickel/Teflon-plating
applications. The industry is also familiar with the limitations
of each type of plating; however, alternative plating technologies
that meet the functional and economical demands of industry are
limited. That is why Electrolizing, Inc. (Providence, RI) has developed
coating processes to meet specific engineering demands.
Each
coating is based on high-grade chromium materials. Major differences
are in the application procedures, control levels and costs. The
coatings are Micro-ETM , Electrolizing, Al-Coat and hard chrome.
In addition to these coatings, the company provides advanced metal
surface preparation. This multi-clean procedure is used, after extensive
research on the part and its soils, to carefully and completely
clean metal prior to processing. The process cleans the surface
of microscopic residual contaminants left from machining, oils or
other debris-generating media.
These
combined coatings meet an engineers five most critical needs:
hardness, lubricity, corrosion, adhesion and precision.
Hardness:
A combination of factors enables these coatings to achieve a Rockwell
C hardness of 72 and greater. The company engineers proprietary
alloys and pure chromium with a consistent, controlled and unique
deposition processing procedure. The coating density provides a
surface that has fewer cracks, inclusions, voids and other surface
irregularities compared to conventional chromium plating.
Lubricity:
This characteristic is the benchmark of providing beneficial
coefficient of friction properties. PTFE is the polymer of reference.
Our coatings, stated Chris Bejbl, general manager, provide
a dry lubricant surface. When discussing steel against steel,
the frictional values range from about 0.20 or greater. Our coatings
usually have values of 0.09 - 0.12, or about a 50% improvement in
lubricity.
Corrosion:
The company subjects its products to corrosion testing using ASTM-B117.
The coatings are also evaluated using humidity tests, salt water,
DI water, bleaches, copper-sulfate, mold cleaners and various commercial
reagents, acids, alkalines and salts. In each case, the coatings
provide substantial protection against corrosion.
Adhesion:
Adhesion is the most important aspect of the coatings. Without adhesion,
neither metallic nor polymer-type coatings have any benefits. The
coatings are subjected to 180degree bend tests without signs
of chipping, spalling or separation. This meets ASTM standard B-489-85.
The technology focuses on the cohesive properties of the molecular
elements of the coatings, assuring that these molecules form an
absolute cohesive bond to themselves and to the base material.
Precision:
The company engineered these coatings to be precise and thin. Normal
coating thickness ranges from 0.00005 - 0.001 inch per side; however
that varies depending on material, engineering applications and
expected performance criteria. However, there is not best
thickness. Each application is different, and many variables determine
a coating thickness. Mr. Bejbl explained, A 0.001 - 0.004
inch thickness will perform well; however, we prefer that our customers
talk with our engineering department in order to tailor the deposit
thickness to their specific application.
Because
we can provide these thin, precisely controlled coatings,
noted Mr. Bejbl, the customer can eliminate the need for traditional
hard chromium plating and grinding.

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Aluminum
sample coated with Al-Coat.
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Rather
than simply focusing on a coating process, the company provides
a technology. The companys strength is in its chromium coating
applications, technology and research and development. All this
occurs in a clean, modern 20,000-sq-ft facility that has been tested
and certified compliant to all state and federal regulations. In
addition to local and federal compliance, Electrolizing has also
recently obtained approval for the new standard ISO 9001-2000. The
coatings the company has developed since its inception more than
50 years ago, include the following:
Electrolizing
was developed in 1945. Since then, the company has refined the process
to keep it an ultra-pure, versatile chrome coating. The coating
is a blend of pure chromium that produces a hard surface, measuring
70-72 on the Rockwell C scale.
The
coating is applied at a temperature below 180F. A cold
process is used to protect precision-machined parts from hydrogen
embrittlement, distortion, annealing and changes in the base metals
tensile, fatigue and microstructure properties.
The
coatings can be applied from 0.00005 - 0.001 inch per surface, according
to customer specifications. Precision tolerance requirements can
be engineered for any deposit thickness. The final finish is a smooth,
fine-grained surface that is free of blisters, nodules, porosity
and excessive edge buildup.
Micro-E
coating is an engineering extension of the Electrolizing coating.
This coating incorporates a multi-step cleaning process along with
modified coating application techniques that result in a harder
surface finish, somewhere near 75 Rc. The deposit thickness ranges
from 0.00005 - 0.0003 inch per surface, depending on customer requirements.
This thin, precise deposit eliminates dimension change, part distortion
and edge buildup problems.
Certified
technicians at the company give parts receiving this finish preferred
handling, inspection and processing. Inspection includes fluorescent
x-ray and laser micrometers. This coating is preferred when size,
fit and after coating tolerance are the primary concerns, or when
additional hardness is required.
Al-Coat
is a newer coating developed by Electrolizing. It is designed to
meet the challenge of protecting all aluminum alloys. The coating
deposit is a dense, non-magnetic, high-chromium alloy deposited
directly on the aluminum substrate, no matter what the alloy. However,
the company does need to know what the alloy is, in order to tailor
the application procedures to that specific alloy.
According
to Mr. Bejbl, Aluminum is difficult to coat with most conventional
electroplatings and/or conversion coatings because aluminum oxidizes
rapidly. Also, it acts as a cathode during the coating process,
which leaves voids in the coating, causing corrosion. Another issue
is that the thermal expansion of aluminum differs from most metal
alloys used in plating. This factor causes most conventional plating
products to peel, chip and flake.
Al-Coat,
as with the other company coatings, has an extremely hard surface
that provides an unusual combination of bearing-type properties,
such as low friction coefficients, longer wear life and excellent
corrosion protection. It has also withstood a 180-degree bend test.
The
deposit thickness for most applications can be engineered up to
0.001 inch per side. The deposit thickness is uniform and consistent,
without staining or discoloration. The coating will not chip, flake
or peel. The finish can be either a non-reflective, matte satin
gray, or it can duplicate a high polished finish. The coating meets
specifications QQ-C-320, AMS-2438 and is USDA compliant.
These
coatings have applications for bearing steels, aluminum, brass,
bronze, beryllium copper, copper, stainless steel, tool steels,
Inconel and Monel. Industrial uses include bearing and sliding surfaces;
plastic and rubber molding; metal-to-metal surfaces; high-pressure
valves and pumps; cryogenic and high-temperature applications; high-vacuum
applications; aluminum machined parts; and fasteners and threads.
Our
competition comes from many sources, noted Mr. Bejbl, including
small and medium-sized platers, both regional and local. However,
we are a stand-alone company. Our business of only chrome
applications makes us different. All of our experience and
success is in the applications of chromium.
Standard
Hard Chromium Plating on Aluminum |
Aluminum
cylinders, pistons, bearings and brake drums are often hard
chromium plated to produce hard, wear-resistant and, sometimes,
oil-retaining surfaces. Hard chromium plated aluminum has
good corrosion resistance, which is important for cylinders,
particularly in atmospheres where sulfuric acid may form.
Since the coefficient of expansion of aluminum is about three
times that of chromium, heating hard chromium-plated aluminum
parts will cause the deposit to crack. This is not necessarily
harmful to the adhesion because the crack structure ensures
that no stress is present in the coating, which could cause
it to flake off.
A
single zincate is sometimes applied to hard chromium plating.
Parts are polished, degreased, etched in an alkaline solution,
rinsed and dipped in an alkaline sodium zincate solution.
Parts are then rinsed prior to entering the chromium-plating
bath. In the bath, the zinc dissolves before the current is
applied. A double zincate process is better than a single
zincate process when preparing chromium for hard chromium
plating.
In
a double zincate process, the first zinc coating is stripped
in nitric acid and a new zinc deposit is applied. This helps
when plating many difficult-to-plate alloys. The second zinc
coating is more compact and has more fine grains. This provides
for a more uniform chromium finish.
The
hard chromium plating process that follows zincating does
not differ much from the process used on other substrates.
Plating baths have 150 g/liter chromic acid and 2.5 g/liter
sulfuric acid. They are operated at 300-500 amp/sq ft at 4-8v,
producing deposits with 1,000 VPN hardness.
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