Trends
in the Automotive Industry Affecting Pretreatments
Helping automotive finishers deal with changes that affect
how substrates are treated
By
Mike Wichman
Global Director, Automotive Pre-Coated Finishes and Pretreatments
PPG Industries, Pittsburgh, PA
Initially,
one would probably say that not much has changed in the area of
automotive pretreatment for a number of years. Globally, most automotive
assembly plants have used immersion processes with tri-cationic
(Zn-Ni-Mn) technologies for several years. However, upon further
consideration, there have been several significant changes in the
conventional automotive pretreatment process, with more changes
to come. When examining the reasons for change, it is apparent that
there are two major drivers: 1) Environmental regulation; and 2)
Substrate selection
Environmental
Regulation of heavy metals has been a concern in the pretreatment
process for several years. These regulations were initially driven
from Europe, resulting in a push toward nickel-free technologies.
Industry attempts to qualify a commercial nickel-free technology,
without compromising overall adhesion and corrosion performance,
fell short of the original objective. However, the research and
development work completed toward this objective resulted in commercialization
of tri-cationic pretreatment technologies with much lower metal
levels. In the United States, the Metal Products and Machinery (MP&M)
initiative was published in the Federal Register in January 2001.
This initiative sought to reduce effluent of chromium, nickel, manganese
and zinc up to 92% from current standards by the year 2005. Although
this initiative has since been revised, it does serve as an indication
of future technology direction.
Chrome
containing post rinses have largely been replaced by chrome-free
rinses or the elimination of post rinses altogether. The initiative
for this comes from the European End of Life Vehicle Directive.
This regulation assigns European automakers full responsibility
for the recycling of their vehicles at the end of its usefulness
or life.
Demands
to limit the use of water and energy reduction initiatives have
created a drive toward low-temperature and ambient processing as
well. The reduction of water consumption and subsequent cost reductions
also have the added benefit of lessening the burden on down stream
processes such as wastewater treatment systems. Reductions in processing
temperatures have significant impact on the use and expense of gas
and electricity (cost) historically needed to heat the large processing
baths.
Substrate
Without question, the selection of substrates used in the manufacturing
of automobiles is an area under continual evaluation by all automakers.
Changes in substrate selection can significantly influence the pretreatment
chemistry to be used. Substrate selection is important for several
reasons, including corrosion performance, weight impact on corporate
average fuel economy (CAFE) standards, design flexibility as
well as overall cost consideration.
Over
the past few years the automotive industry has widely adopted the
use of galvanized or galvanealled substrates on exterior panels
to extend corrosion protection. With the ever-increasing demands
to lower the weight of vehicles to meet CAFE standards, the use
of aluminum offers significant reductions in the overall weight
of the vehicle.
With
U.S. manufacturers, the use of cold-rolled steel is limited to low
corrosion areas such as automobile roofs. The increased use of aluminum
and multiple substrate combinations offer several challenges to
the traditional pretreatment process. Technologies that have traditionally
been effective in treating the cold rolled steel and galvanized
substrates often need to be modified to accommodate the various
alloys of aluminum, depending on the volume of aluminum that is
being processed. There is a pretreatment chemistry that can accommodate
high aluminum loading while maintaining excellent pretreatment quality
on CRS and zinc coated substrates processed through a common pretreatment
bath.
Another
trend that is affecting the pretreatment process is the expanding
use of mill-applied coatings. These coatings range from dry-film
lubricants and pre-phosphates to weldable primers. While dry-film
lubricants and pre-phosphates are used primarily for improvements
in stamping difficult to draw parts, weldable primers potentially
can change the footprint of a conventional paint shop, through the
elimination of processes such as hem-flange sealants and cavity
wax operations.
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