MONTHLY REVIEW
Published
by the
American Electroplaters Society
Publication and Editorial Office
3040 Diversy Ave., Chicago
VOL.
XVII FEBRUARY, 1930 No. 2
EDITORIAL
A PRESENT
URGENT NEED—GET OUT OF THE RUTS
“We have always had war,
therefore we will continue to have war.” This
expresses the kind of logic that is characteristic of a large number
of people; when they think of war, they think in terms of the past, their
mind moves along the ruts made by the experience of the past. They
do not think of the possibility of getting out of the ruts into better ways of
life and of doing things. Because of this kind of thinking, those who
would
help us out of the ruts find they have a very difficult job, and so
the thing that the world needs and everybody wants (except the few who profit
by war) comes very slowly, because our habit of thinking keeps us in
the
old ruts. Change is the order of the day—and change means get
out of the ruts. This change must start with our habit of thinking.
I
would say that one of the very necessary qualifications of an electroplater
is that he shall be able very frequently to change his mind, to change
his method of thinking in terms of the past—to thinking in terms
of the future. If we change our thinking, we will change our method
of doing things. We spend too much time in trying to remember how things
were
done yesterday, when we should be thinking of how we will do things
tomorrow. It is so easy to feel that we have perfected a plating method,
process
or solution, but the moment we feel we have perfected something, that
moment we set up a barrier toward change, and if we do not change we
stay in the
old ruts. Of course, there are some good ruts in which to travel, if
we don’t stay in the good ruts we may go into the ditch, but
we should always be on the lookout for better ways of doing things.
After all,
the men that make a real contribution to their special field of endeavor
are
the men who are remembered, because they got out of the ruts of the
beaten path and became trail builders that lead to new and better ways
of doing
things. May every member of the A. E. S. stay in the good old ruts
as long as they are good and get out of them just as soon as study
and research
point us to a better way of doing things.
A WARNING
W. M. Phillips
of Detroit Branch
The plating industry, in spite of the many vicissitudes
through which it has passed, has become quite an important factor in
the automobile
industry,
to say nothing of its place in other lines of business. It appears
to have reached a very critical phase. It can go forward rapidly, or
backward
with
still greater speed.
The practice of plating automobile parts is being
challenged by the proposed use of stainless steel and irons. Also by
the use of paint,
lacquers
and enamels.
Sketching a few fundamentals we will ask a question: “Why
electro-plate?” First
we wish to protect the base metal from corrosion and wear, allowing
the engineer the choice of metals best suited to the part as to strength,
workability and cost. Second: we wish to produce artistic and pleasing
effects.
There is not very much question about plating producing the
pleasing effects which it is asked to do. There is some question about
the present
type
of plating being able to protect against corrosion and wear in a satisfactory
manner. I do not believe that any of us could successfully plead ignorance
as to how good a job should be done.
I am going to risk going over some
ground which has been covered probably much better than I am able to
do. Let us look into some of the causes
of poor work and see what would remedy the situation. Iron and steel
present
a great many advantages from the standpoint of engineering. In most
cases where it is used for decorative parts, a good plate is one of
the essentials.
One difficulty is that these parts are often made from inferior iron
and steel in such a way that they are porous or full of slag inclusions.
Next,
they are made in such a shape that they are difficult or impossible
to polish, plate and buff satisfactorily. A great deal can be done
by giving
our engineers information which is necessary to remedy these conditions.
Even
if the steel and iron were relatively perfect, the plate is still unsatisfactory
as it is usually done.
In spite of the fact that Dr.
Blum, Professor E. M. Baker and others have pointed out that a thousandth
of combined nickel and copper are
necessary
to produce a good job, very little of the work done today carries
a plate as heavy as this. In man,, cases it is not half as heavy.
It would
appear that a great many manufacturers are leaning too heavily on the
qualities producible by the light chrome coating which we put
over copper and nickel plated steel.
When it comes to chromium plating,
even this is seriously slighted. It has been found by our experiments
that an article plated for 30
seconds
in the usual chromium bath at 20) amperes per square foot is quite
unsatisfactory. When it comes to withstanding even a casual polishing,
15 seconds rubbing
with ordinary nickel polish will generally cut through a plate of
this character. Now the average new car buyer at least is going to rub
his
chromium whether it needs it or not, and he may rub it off, .If it
only has 30 seconds
on there. If we plate the article for one minute at the same current
density, it is still unsatisfactory, as this plate can be generally
rubbed through
in one minute, whereas if it is plated for two minutes at 200 amperes
per square foot or 400 ampere minutes, it generally requires about
fifteen minutes, and often more to remove this plate, rubbing vigorously
with
nickel
polish.
The question naturally occurs, ”Why stop at 400 ampere
minutes?” I
am going to refer to a paper of Mr. E. M. Baker and Mr. Walter Pinner,
read before the Society of Automotive Engineers, March, 1928, which
answers this question, and also throws considerable light on the requirements
of a good nickel chrome job.
Slide No. 1. Let us first refer to Fig.
2. Here we see a series of
micrographs of pieces first nickel plated, then chromium plated with
various amounts
of chromium. The first specimen 100 ampere minutes, the next 200
ampere minutes, on up to 1400 ampere minutes on the last one. Following
the
chromium plate, each piece was plated with copper from an acid copper
bath. The
copper does not plate on the parts completely not covered with chromium
so that Mr. Baker obtained a very good map on each specimen. The
black line at the bottom represents merely the edge of the specimen.
The
copper shows up white and the chromium black. Please notice that
100 and 200
ampere minutes do not cover very well, the chromium is quite porous.
Then as we
proceed, the 500 ampere minute plate starts to develop a lot of fine
cracks which get worse as we go on, indicating the reason why we
do not want-
more than 400 ampere minutes, unless other methods are shown to deposit
chromium of different characteristics.
Slide No. 2. We shall now refer
to Table No. 2, Series Nos. VII and VIII, representing a series of
panels all of which were plated with
nickel
100 ampere minutes, copper 100 ampere minutes and nickel 300 ampere
minutes.
No. VIII represents a series
of panels chromium plated with various amounts of chromium which had
first been plated with a base deposit
of nickel
200 ampere minutes, copper 300 ampere minutes, nickel 4(10 ampere minutes.
The column of figures to the extreme left represents the number of
ampere minutes of chromium used in each case. The figures given under
VII and
VIII represent salt spray hours. You will note that they increase gradually
and decrease the same way, with a few exceptions which I believe could
probably be called experimental errors. The optimum condition seems
to occur at somewhere around 400 ampere minutes. This is a very fortunate
circumstance as it gives us the opportunity to standardize on about
this
amount of chromium. Mr. Strausser has kindly given me permission to
use some slides which he used in a paper entitled ”Chromium Plating,
Friend or Foe.”
The first slide ( Slide No. 3) represents a wire
chromium plated to a thickness of .0019 and shows-what might be considered
a very nice
distribution
and
plate of this material.
Slide No. 4. This slide shows a badly rusted
and pitted piece of work which was exposed for one year in actual service.
This piece was copper
plated
only before chromium.
Slide No. 5. This slide shows also a defectively
plated filler cap taken from service. In this case the copper nickel
base was too light.
In
summing up, it would appear that the cause of electro-plating is by no
means hopeless. However, it is going to be necessary to do a
better
job. The use of stainless steel and iron has increased over 500 in
the automobile industry since last year. In some cases it is absolutely
the
right thing to use, and I don’t believe that any plated work
can compete with it for these uses. Among these are wire wheels, another
is running board molding. In these cases, electro-plating through too
severe
usage is removed, either by abrasion from stones striking the wire
wheels,
or from scuffing in getting in and out of the car on running board
moldings.
There are many other cases where steel articles plated with
copper, nickel and chromium would be much more economical if the
work is done
properly,
but I believe you will agree with me that a warning at this stage
of the game is in order.
I have mentioned one other
thing there—I
said that paint and enamel were a certain amount of threat to the plating
industry. We have practically
done away with plating on automobile rims and are using Parkerizing
and enamelling. That was due to two causes, the main one that we wanted
a black
rim due to the black side walls on the tires, more than the fact that
the plating was not satisfactory. The plating was really quite satisfactory,
but we needed a black and- couldn’t very well plate it black
as economically as we could do it the other way. But there are certain
improvements
in
the paint and lacquer industry that call for a better plate so as to
have a uniform finished product, that is a product that will stand
up the same
all the way through. And I am going to ask everybody to try and co-operate
to get a letter standard of plating.
CHAIRMAN FEELEY: Are there any
questions the members would like to put to Mr. Phillips?
MR. WOODMANSEE: I would like to ask Mr. Phillips
if his company will pay the price to get that product the way it should
be.
MR. PHILLIPS:
I would say yes, Mr. Woodmansee, that that will be done. The very fact
that companies—not ours, but others—seem
to be willing to pay for stainless steel is the answer.
MR. HOGABOOM:
It would be fine if a company such as Mr. Phillips represents
would develop a standard method or standard process for testing. His
figures on salt spray mean nothing—it just means what he got
in that particular line. It depended in a large measure upon the degree
at which the salt
solution was atomized. If he had a fine spray, he would get one result;
if a coarse spray, he would get another result. If the air leaked out
of his chamber at a different rate, he would get a different rate of
corrosion.
If he would, as they have done in the Bell Telephone laboratories,
exhaust the salt spray chamber, he would get one-fourth the life and
corrosion
as he would if he didn’t exhaust it and kept it tight. So that
salt spray, as is, and the figures, are only of the value to a particular
test,
under particular conditions, and unfortunately, the investigators do
not give those conditions, so comparable results can be had throughout
the
industry.
MR. PHILLIPS: I think Mr.
Hogaboom is 100% correct about the salt spray being merely a comparative
test under the conditions under
which it
was conducted; that is, I do think Mr. Baker’s figures have value,
a value by comparison in that particular test. Probably all his factors
in
that case were fairly uniform. There is one thing else, however, before
we condemn the salt spray too harshly. The material which we ordinarily
take as an example to electro-plate quite often has variations in it
greater than the salt spray; that is, we may select ten pieces of steel,
ten articles,
and of those ten articles, the basic material is going to vary all
over the lot, probably. We will have a lot of holes in one, another
one pretty
good, and if we were to put the faintest kind of a plate on that and
merely test it, there would be a big difference right there. So we
are applying
a rough, a very; rough and inaccurate test when applying the salt spray,
and do need a better one, but we will need it a whole lot more when
the raw materials become more uniform.
MR. SIEVERING: I would like to
know if the automotive industry is making
any standards at all as to what constitutes a standard plate.
MR. PHILLIPS:
I can only speak for the company that I represent. We have recently
adopted a specification calling for a definite thickness
of
plate, in addition to the salt spray, and I may say probably in the
future, judging
work, we will pay a little more attention to the thickness of the
plate than we will to the salt spray results.
DR. BLUM: I want to come up
and speak in front here because what Mr. Phillips and Mr. Hogaboom
said fits in so well with the program of
the Research
Committee for the next year that I am going to risk a repetition
of some of the things that were said last night when only the stragglers
were
left here and after our own technical program.
As some of you know,
at the meeting of the Research Conference held in Newark on April 6,
Mr. McCord, of this city, gave a rather scathing
indictment
of the plating on automobiles. I am not going to discuss the question
as to what extent this criticism was justified, but at any rate,
the two points
that he emphasized were first of all that we do not know what constitutes
a good job of chromium plating, and a means of defining and ascertaining
it; and secondly, the manufacturers are not using the knowledge that
they already possess. Now, the Research Committee certainly, or the
Bureau of
Standards, can have very little to do with the latter part, that
is, the question of the selection of the conditions by the manufacturers
is an
economic question which they are going to be forced to just to the
extent that the public demands it. But the Research Committee did
decide
that
the subject for research for the two associates for the next year,
or as long as necessary, is to be the protective value of plated
coatings, with
special reference to chromium. No we have not attempted to make a
detailed plan of the investigation because there are so many factors
that will
have to be planned in the light of what we discovered in the early
work;
but
we are starting out to work on the question of the porosity of the
coatings, and then, in the light of that, the relation between porosity
and the
protective value, both under accelerated conditions, including salt
spray and any
better test that can be devised, and under normal atmospheric conditions,
in different localities, we hope, in co-operation with the American
Society for Testing Materials, who maintain test fences at five different
localities
in this country.
Now the reason that I am speaking
emphatically on this point is because of the conditions which Mr. Phillips
and Mr. Hogaboom
and Mr. McCord
and others have pointed out, that this whole subject is of very grave
importance
to the electro-plating industry. It isn’t a question simply of
how you are going to do your plating, it is a question of whether you
are going
to do your plating. In other words, as to whether nickel and chromium
plating will increase in extent or decrease in extent.
Now all of this
means money to support the research work and the Research Committee.
The research work, the research fund, is just completing
its first three-year program, and during the next six months, it is
going
to be necessary for the Research Committee to go out to the manufacturers,
not simply to collect the funds they have promised—they have
already paid that but to get new promises for we will say another three-year
period, in order to support the work of the research associated and
in
order to
get more definite information.
It is no disparagement of
Professor Baker, who was unable to come to’ this
meeting today—it is no disparagement to say that as valuable
as his results are, they are not the last word; there is still a ,great
deal more
to be learned regarding the relation of various factors to the quality
of the plating, and I say that then, when the Research Committee comes
out for funds, don’t forget that it is your committee and that
it is the fund of the ElectroPlaters’ Society and that the Research
Committee can not get those subscriptions and those funds unless the
members of the branches get back and help.
It is very appropriate that
Mr. Phillips and many others here represent the automobile industry;
certainly the biggest branch of plating in
the country today. And I say with no disparagement to them at all that
out
of over 100 subscribers to the Research Fund during the past three
years, there is one automobile concern represented, Mr. Phillips’ firm,
and there are four accessory firms. Now you know better than I do how
many automobile factories and how many accessory firms there are in
the country,
and I just say that every firm that is interested in plating, if they
feel that the research work should be carried on, (and that is for
you people
to decide, if you feel that the research work should be carried on
and extended along these lines that Mr. Phillips has suggested), then
get
back of your Research Committee.
I am not speaking for the
Bureau of Standards, I am speaking for the Society and for the Research
Committee,
because I know how hard they
have worked
during the last three years to collect and administer the funds that
were used in the research work. We are simply your agents, we are at
the Bureau.
Our laboratories are at your disposal, and we will do just as much
work as we can, both with the funds obtained from the government and
with
the additional funds that are secured from those who are interested
in electro-plating.
But I have made this talk today even though it is more appropriate
tomorrow, in connection with the business session, because I see there
is a big
crowd here today, and I don’t know whether there will be so big
a crowd tomorrow.
MR. HOGABOOM: Mr. PhilIips spoke about the replacement
of the present iron and steel with stainless metals. Will the same
thing occur with
aluminum,
chromium plated?
MR. PHILLIPS: That is a very
difficult question, for this reason. I wouldn’t
say that chromium plated aluminum is a failure, but it is not yet as
satisfactory as we would like to have it. If it became more satisfactory,
then it would
become a possible contender for a place in the industry. But it does
need to become a little more satisfactory than it is at the present
time.
CHAIRMAN FEELEY: Are there any more questions? This is very important
to the industry and to every plater. I might draw your attention
to a suggestion
made to you by Mr. Phillips. He says it is in the hands of the plater
to present his position to the automobile manufacturer in the construction
of his supplies, radiator shells, and so forth, that they get away
from the recesses and the difficulties that we have in getting into,
both
for
polishing and to throw. It is possibly well that the American Electroplaters,
in session, might take this up at their business meeting tomorrow
and- make some recommendation, that a great deal of the difficulty found
in industry, as Mr. Phillips said, the cutting through the edges
and
the
difficulty of throwing into the designs as constructed now by the
automotive engineers,
might be avoided.
MR. LOUIS LIGHTMAN: You do not think, Mr. Phillips,
it is more advisable before you decide upon the thickness of plating
that you also decide
upon the porosity of the plate? Has that a material effect on the
lasting qualities
of the plate?
MR. PHILLIPS: Certainly, if a last coating of non-porous
metal could be put on, it would be an aid. However, we find that most
of the plates
are
porous, and we must treat things as they are, not as we would like
to have them. When, later on, someone comes out with a plate that
is absolutely
non-porous, we can cut down the thickness with impunity.
THE PAST AND
PRESENT OF ELECTROPLATING
Read at 18th Annual Meeting of Chicago Branch,
A. E. S.
By Jos. H. Hansjosten
Mr. Chairman and Gentlemen:
When your chairman invited
me to address you on this auspicious occasion, I felt that a great
honor had been bestowed
on me and when he requested
that I speak on ”The Past and Present of Electric-Plating” I
knew I was on safe ground. So I wrote to him, and told him that I knew
of no one better qualified than myself to speak on that subject; particularly,
the ”past of electroplating,” for I informed him, I could
go so far back in plating, that to tell it would sound like ancient
history.
His request sent my memory
racing back over the years gone by, back to scenes and conditions as
they were then, scenes almost
forgotten,
and
conditions that would not be tolerated today. In comparing that time
to the present,
I was impressed with the changes that have taken place with the changing
years—changes for the better.
We know that the world has improved,
or rather that conditions in it have changed, not only in our industry
but generally. We are no doubt
more impressed
with the changes in the plating industry, because we are in daily
contact with it. But, even out of our line of work the world did move,
and
move forward fast. So notable are the improvements that by contrast,
they
are striking.
Strange how some happenings
awaken long dormant memories in us, and stir our ever-present tendency
to look backward. And looking
backward
I know
some of you will go back with me in memory, and view again scenes long
forgotten and see again with memory’s eye, some face long since
dim. Many of you here today can look back to the time when a plating
room was
considered just a necessary evil, just an added expense to a factory,
and the time when the public taste was not developed to look for beauty
as
well as for utility.
You may think, as I go on
that I am rather hard on the old-time plating room and that I exaggerate.
But, the truth
is, my pen has not the facility
to describe the conditions as they really were. Some of you know that
the picture is accurate, for you saw it. Others of you who came into
being
at a later and more enlightened time, will be grateful that the voice
of those ”crying in the wilderness of long ago” was heard
and that they prepared the way for you, and made your path if not easy,
at
least less hard.
Let me first impress on you
that to the old-time plater the mixing of solutions was a secret to
be jealously guarded. It was
his firm
belief
that the beginning
and the end of the plater’s art was the mixing of solutions.
He who knew how to mix a nickel, copper or brass solution was a plater;
and the
logical sequence of such a belief was that for his own protection he
must guard his secret well. You would not think of erasing the names
of chemicals
from their containers today, yet many of us saw that done frequently;
for if the plater was to fully guard his secret no one in the room
must
know
what he put in his solutions.
I can shut my eyes and still see an old-time
plating room presided over by a kindly old man, who had a partition
built across one end
of the
room so that he could keep his work from spying eyes. In the little
room so
made he kept his chemicals and mixed his solutions. In the partition
were windows and on the windows were curtains which were drawn together
whenever
he went into his sanctum to mix his solutions. He would bring his
mixtures from his little room in a large copper dipper and pour them
into the
tanks. In that particular plating room we used only one kind of acid
and that
was brought out of the little room in an earthen pitcher whenever
it was needed. It was muriatic acid, but I did not know that until some
years
later. Besides the nickel solutions, we had in that plating plant,
a copper solution that sometimes plated copper, and a brass solution
that
never
plated brass.
I can vividly remember another
plating room which had windows on one side—not
many!—but they were windows. Against one of the windows was the ”strip
tank,” a large earthenware crock, where future platers stripped
the nickel from the copper wires on which the work had been hung in
the tanks,
so the wires could be used again. I might add, for your information,
that we took the kinks out of the wires by striking them on a flat
piece of
iron and then sorted them as to lengths. How often we used them I do
not remember, but labor was cheap then and I assume it paid to save
them. The
strip just mentioned was of the nitric and sulphuric acid variety and
when the wind was in the right direction and the strip was working
good, you
knew without being told that the breeze coming through that window
was not scented with the breath of new-mown hay.
The plater in that
plant had a little ”stock room” in one
corner of the plating room, which we irreverently called the ”Holy
of Holies” and
which was always locked. In it he kept his chemicals and mixed his
solutions, and it was the only part of the plant where the floor was
dry. In the
rest of the room we just waded from tank to tank. Rubber boots were
too high
in price and wooden shoes were not high enough to keep our pedal extremities
dry, for the water was always at high tide. But it was a rather nice
place to work in. That is by comparison.
As I stated some time ago
the knowledge of mixing solutions was-the plater’s
secret. It may even be called a dark secret when the work turned out
by some of them is considered. His attitude toward his fellow platers
was
the same as toward his helpers. He would not in those days exchange
ideas with another plater because he might possibly have a better solution
than the other fellow and he did not want to give his formula away.
So
he hid
his light under, a bushel. The trouble was, in cases at least, that
when the bushel was raised there was usually no light under it. As
a rule
when two or more happened to meet they could not or would not agree
on anything.
It was not policy to agree, for each might give some of his secret
away.
But there came a day when
they received a great shock and many of them finally had a subject
on which they thoroughly agreed. A book
was written
and published which exposed their most cherished secrets and told how
their solutions were made. Anyone who bought it and read it could now
know the
plater’s secrets. My memory is rather dim about this but I believe
that some of them agreed so thoroughly on this subject, that they requested
the supply houses to refrain from selling the book. It was to them
the most outrageous thing that had ever happened. Why even the boss
would
now be able to mix solutions and every Tom, Dick and Harry would now
be a plater.
Those were indeed dark days
for the old-timer. But even then the dawn of a new day was breaking—a
new era in the plating industry was at hand.
In describing the last plating room I said it had windows in
one side. Now I will tell of one that had windows in the sidewalk.
Ridiculous,
you say? Not at all. For, bear in mind, that we are still speaking
of the days
when any old place was considered good enough for the plating room.
This room was in the basement and the plating tanks were in that
section that
extended under the sidewalk. All the daylight to be had came through
those thick, round pieces of glass set in the iron framework of the
sidewalk above. Some of the glass was always missing, but we had
on hand a number
of pans to catch the water that came through when it rained.
The connecting
rods in this plant were very handy. We had no rheostats, but we had
a lot of copper wire twisted into a cable that was fastened
to the bus bar, and we just slipped the other end of it around the
cathode rod when the tank was loaded.
The dynamo was a wonderful piece
of machinery. As an antique it was grand! But it could be regulated
quite handily. In the front part of
it were
a number of holes and in a box we had a number of what we called
plugs. To
step up the current we put a plug in one of the holes. The more plugs
we put in the greater the shower of sparks became when we drew a
file across
the anode and cathode rods.
Of course, some plating rooms were more
up to date. I saw one that had electric light bulbs connected to the
tank rods. If the lights
were bright,
the dynamo was doing its bit. If they were dim a piece of sandpaper
held on the commutator or some belt dressing applied to the belt
usually helped.
Among the platers of that
day were many men who realized that if they were to become masters
of their art they must know the scientific
principles
upon which it rests. And more and more the progressive plater studied
the
why and wherefore of electrodeposition. Instead of looking for new
formulas he began to study—he tried to find why a solution acted
thus and so. The rule of thumb was slowly but surely giving way to
scientific
practice.
And here, too, let me say, among them were men who did splendid
work; while they were not confronted with modern mass production,
neither did they
have modern instruments to help them overcome their difficulties.
The hydrometer and a piece of litmus paper were his only means of making
a test. Compare
that with our color meter for the testing of acidity and metallic
content,
and your simple titration for your chloride test. That will give
you an idea of the difference in the methods then and now. It is a matter
of wonder
that they were able to do as good work as they did.
Among the factors
that aided much in bringing light into the darkness were the representatives
of supply houses and the trade journals.
There
were a never failing source of information and they contributed generously
to the solution of many problems that confronted us. This
tribute is due
them from many of us for few platers of that time did not at some
time receive their aid.
It was the progressive plater, the man with vision
and a desire to elevate himself, who saw that if the art of plating
was to become what
it should
be and what it has since become, he must cease to isolate himself
and exchange the knowledge he possessed with his fellow plater. Both
of
them would gain
in knowledge and both of them would be better platers. How could
it be otherwise? When each of them knew how to do one thing and they
exchanged
that knowledge both of them knew how to do two things. Gradually,
as the dawn grew into day, more of them got together and laid the foundations
on which this great society is built.
And they built better than they
knew. I venture to say that our esteemed founder, who today is honoring
us with his presence, never in his most
optimistic moments or in the greatest flights of his fancy fully
visioned the growth in influence and members of this society of today.
For our
society, more than any other factor, is responsible for the great
improvement in
methods, equipment, and general conditions in the modern plating
plant. For today, instead of the old earthen crock by the window, the
strip
tank is covered with a hood and its poisonous fumes are mechanically
carried
away. The contaminated air of the old room is no longer in evidence,
and with it is gone the sallow skin and the cough that it usually
brought about.
The rule of thumb is replaced by the rule of science and the
plater that did not realize that a new era was at hand has become as
driftwood
cast
on the shore of the stream of progress.
And the journey’s end
is not yet. There is a long, long trail ahead. A condition confronts
us today that for ourselves and our employees
we must prepare to meet. For today as never before we face a competition,—the ”New
Competition” as it has been called. A competition so keen that-the
like has never been. I do not mean a competition among ourselves,—though
to an extent it is even that,—but the competition for business
brought on by modern mass production, the production for which the
sales department
must find a market if wages and dividends are to be paid. The plating
cost of a product is only a part and sometimes only a small part of
the cost
of a product. But, whether much or little the plater who can keep his
cost at the minimum is the one who will do his -share in helping his
concern
to meet the new competition.
Today, and in the future,
it behooves the plater to pay quite as much attention to the elimination
of waste,
waste of time and material,
in his departments
as to the chemistry of his plating. Holding your cost to the lowest
point can be done by applying scientific principles to your work. It
can not
be done by lowering wages, for a concern to be successful must have
successful workmen, and an underpaid workman is not a successful workman.
It must
be done by instilling a spirit of co-operation and loyalty in our workmen
by letting him realize that unless profits are made wages can not be
paid. That unless the firm that employs him can meet its competitors
on an equal
basis for the world’s business, their business and his business
will cease to exist and as a natural sequence dividends and wages will
stop.
Truly the employer today is not lying on a bed of roses, and if he
were, the thorns of competition would prevent him from enjoying sweet
repose.
You recall, how years ago we insisted that plating was a science,
a
fact now generally conceded. I will say now that we will need every
bit of
knowledge that we acquired during the years, including the science
of handling men
as well as scientifically handling our departments to meet the competition
of the immediate future.
And we will be forced to acquire -more knowledge,
we will have to find a way to handle stainless steel. As though the
new competition were
not enough and did not give us problems enough to solve we will find
this
a hard one to solve, and we will find that this problem is with us
even now.
But life is like that—just one thing after another.
And like men, men worthy to be members of this society we will meet
every problem
of the future and solve it; meet the new competition and beat it,—in
short, we will win.
ELECTROPLATING SHEET COPPER
Read at Baltimore-Washington
Branch Annual Meeting, January 25, 1930
I have been asked
to speak on—”The
Electroplating of Sheet Copper.” As far as I know, no previous
paper has been read on this subject. It is my plan to briefly discuss
how the use of copper
as a
base metal would solve some of the present problems (as mentioned by
Mr. McCord)
as well as the actual electroplating of nickel, chromium, and tin.
We picture mass production or production on a large scale, as that
of automobile parts, plumbing supplies, etc. Very little is known
by the
electroplaters
of the history, development and rapid growth of electroplating in
the Sheet Industry. It began with the thought that electroplating of
nickel
and finally
chromium on a suitable base metal, would produce a durable and more
beautiful finish at a much lower cost than it would to alloy them.
This alloy though
as durable, would not have near the beauty and would not maintain
its lustre.
The public has not only accepted chromium, but is now demanding
it. What housewife does not want chromium plumbing fixtures? The day
of
unsightly
fixtures and utensils and hours of scouring and polishing is past.
I do not think any man can but honestly and emphatically admit that
chromium
is the finest finish ever produced on an automobile. How many men
who have
had good chromium plate on their automobiles, want to go back to
finishes which require continued polishing?
We have in the Baltimore plant alone
in the past five years, plated millions of square feet of nickel surface,
not including in this figure
the chromium,
tin, etc., and we have had very few complaints on the plating or
its durability.
Every sheet we produce must stand the most rigid tests.
We plate in large sheets. After plating, the sheets are sheared, stamped
and spun
in the
manufacture of reflectors, coffee urns, tubs for electric washing
machines, etc. It can readily be seen that the plating must be right
in order
to stand all the crimping, stamping and forming into washing machine
tubs,
then give years of service filled with hot swirling alkali solutions
and clothing.
Yet the automobile industry is condemning electroplating.
I was surprised at the attitude of General Motors men and have since
learned that a
few others have criticized electroplating, while other industries
have taken
the reverse attitude.
While we electroplaters of the country are partly
responsible for this existing condition, the greatest fault lies with
the automobile industry
itself. You would not build your factory on a poor foundation, neither
should you electroplate on a poor base metal and expect a satisfactory
result. We know that the slightest porosity in the plating will allow
steel base metal to rust through or oxidize eventually causing complete
destruction.
Most of the large
automobile plants use steel as a base metal. This metal frequently
breaks in the
stamping, necessitating an
army of men
welding,
patching and filing these defects, then using the various emery buffings
to produce a suitable finish— finally, copper plating and buffing.
All
these expensive operations would be unnecessary if the proper base
metal were used. While brass produces a wonderful finish, the zinc
oxidizes rapidly and gives trouble. Hair line cracks eventually appear
in the
plating and again the finish is undesirable.
Sheet copper being
the most ductible metal, makes stamping and spinning a simple matter—all
these welders, filers and emery buffers would be a thing of the past.
It is only necessary then to polish the copper
on a muslin or canvas wheel with tripoli and it is ready for nickel
plating. You can see from this, that you have only two or three operations,
while
before you had six or seven. The floor space, machinery and labor have
been cut in half and copper plating has been eliminated.
We now have
a radiator shell, or whatever we stamped and polished, with none
of the faults of the base metals generally used and in addition,
most any plater can do a first class job of plating that will last
as
long,
if not longer, than the automobile itself, at a much lower cost.
The
trouble is caused by the manufacturer using poor base metals and running
his operating costs sky high, trying to get a satisfactory
finish on them,
then giving it inadequate coatings or jobbing it out to the lowest
bidder, resulting in cut throat competition, there being no standard
plating
specifications for the work, the result being poor quality and a
very unsatisfactory product.
As a result, they condemn electroplating and consider the use of
rustless or stainless steel and this is not the answer to their problem,
it
is merely starting over and going back to the beginning of alloyed
metals.
We were one of the
first copper producers to electroplate sheet copper. Our electroplate
business has
grown in the past five years by
leaps
and bounds. The first two years we were practically alone in this field—now
most of our competitors are electroplating. Our rapid growth and development
I attribute to just one policy, that is—quality. Our whole organization
is trained on quality. Quality is the thing that is needed most in
the electroplating field and every means you can install to produce
it.
In the plating of sheet copper, we are starting out with a base
metal
that is not subject to atmospheric corrosion as is steel, aluminum,
brass and
other base metals. Therefore, the plating is only subject to abrasion
or tarnish.
I will not go into detail regarding the uses of nickel plated
copper. It is one of the oldest metals, and its uses are practically
unlimited.
Preparatory
to nickeling, the sheets are rolled and annealed, which is done to
give the various grain sizes or crystalline structures and
various
strengths or tempers. They are then made flat; on a hydraulic leveling
machine and are now ready for the buffing department.
The sheets are
buffed either on automatic or hand wheels of muslin with a peripheral
speed of about 10,000 ft. per minute, using tripoli
composition.
They are then inspected, those having defects in them are sent to what
we term the rough buffs or canvass wheels where those defects are buffed
out. They are then ready for the Nickel Plating Department. Arriving
at the Nickel Plating Department the sheets are clamped or racked.
They are
then passed to the cleaning operation where they are cleaned electrolytically
as a cathode at 4 to 5 amperes per sq. ft. for one to one and a half
minutes in a mild alkali cleaner at about 150° F. It is only necessary
in this operation to remove the greases used in buffing. They are then
water rinsed
and placed in the nickel bath—a standard, cold, single salt solution,
ran at 70° F., using single nickel salts, ammonia chloride and
boric acid. The sheets are left in the nickel solution at from 5 to
8 amps
per sq. ft. until a coating of 12 to 2/10,000 thickness has been deposited.
They are then rinsed and dried, sent to the re-squaring shears where
they
are sheared to size, then to the buffing department for coloring.
I
was asked to give some account of my troubles with nickel. The general
opinion seems to be-that trouble and electroplating are closely related,
but it has been so long since I had any trouble, that I could best
tell you how to avoid it.
To begin with, everything
must be kept clean—all
the contacts as well as the floors—keep your plating tanks clean
and your solution clear—keep your tanks free of muck and sludge.
When adding chemicals or sulphate to your nickel solution, make it
up in some other container
and then filter it into your regular plating solution.
Use the best
or the purest anodes you can buy and keep enough chlorine in solution
to maintain a standard metallic content, balancing this
with an equal amount of boric acid, thereby making it unnecessary
to continually
add sulphate; when you add sulphate you also add impurities.
Neutralize
your solution and precipitate impurities as often as is necessary,
twice a year under average conditions, then bring it back
to a pH of
5.8.
It is only necessary
to follow a few simple rules to produce good nickel plating, such as—
Keep contacts, solution and anodes clean. A,
pH of 5.8 as specified by the Bureau of Standards, should be maintained,
as well as the standard
metallic contest of about 30 G/L or 4 oz. per gallon. The amount
of chloride
to carry in solution is governed by the type of anode in use. A cast
97 per cent anode corrodes more readily, so around 9 or 10 G/L of
chloride should be sufficient. I prefer the 99 plus rolled, depolarized
anode,
which
may require as much as 16 G/L of chloride in solution, using the
same amount of boric acid.
There being no rapid or satisfactory method for
the determination of boric acid in the solution, it is seldom taken,
but the pH and the
metallic content
can easily be determined by the colormetric method, and the chlorine
can be determined by titration. These titration and colormetric sets
can be
bought from most all plating supply houses. Chromium Plating
I think this subject holds the greatest interest of the
platers as nickel is an old subject that was mastered years ago by
most of them.
However,
if you have not mastered cleaning and nickel plating, your faults
will surely find you out in the chrome tank.
Most chrome plating is done
over either nickel, copper or brass and I am thoroughly convinced from
experience and observation, that chromium
over
nickel is by far the finest finish and the greater the lustre of
the nickel, the greater the finish the chrome will have.
I will not discuss
the various chromic acid concentrations, but will say that the sulphate
ratio to chromic acid is very important and in
my experience,
find the 100 to 1 ratio gives best results.
I have plated and
gotten good results in the bright range, with the various temperatures
and current
densities ranging from 90° F.,
GO amps./sq. ft. and increasing the current density and temperature
correspondingly
to 130° F., 325 amperes per sq. ft., with the 400 gram solution.
I also found that I could vary either the temperature or the current
density
by as much as five per cent as long as the ratio was from 95 to 1,
or 100 to 1, but when the sulphate was a little low and showed a 107
to
1 ratio,
the bright plating range became very narrow. If the current density
were lowered slightly, brown spots would appear on the work where no
chromium
had deposited. Then if we raised the current a little, the deposit
would be frosty on the edges.
If the sulphate is
low, more sulphate can be added. If the sulphate
is high, barium carbonate can be used—two ounces of barium carbonate
will precipitate one ounce of sulphate.
I laid stress on
keeping everything clean at the nickel tanks and it is of greater importance
to keep everything
clean around the chrome-tanks—chiefly
contacts and anodes. I might say here that I prefer lead to steel for
both anodes and tank lining—not pure lead, as it will go up in
a short time, but antimony lead, and I refer 6 per cent antimony rather
than
3 per cent.
You will find that it is important to keep the lead anodes
clean and free of lead chromate. This is a yellow substance which
acts as an
insulator.
I found if I had not used the tank for a day or so and I
placed a dummy cathode in the tank and set a 6 volt, 5,000 ampere generator,
at 6
volts, I could only get 4,000 amperes, but in a short time the ammeter
would
rise until it showed 6,500 amperes at 6 volts. This proves the necessity
of
good clean anodes and contacts.
We plate the chrome to any specified
thickness, the average being a 2/100000 coating. I also found while
plating at the various temperatures
and current
densities, while I have not tested it thoroughly, that the lowest
range produced a somewhat softer deposit and correspondingly harder deposits
as the temperature and current density was increased.
I have read a
few articles where platers have controlled the current with the voltmeter.
I cannot see how this can be done if you are plating
material
of various sizes requiring various current densities. I can plate most
any article without either the voltmeter or the ammeter, by observing
the action of the solution, but I don’t recommend this method.
I use a voltmeter on every tank and an ammeter on everything I plate.
These instruments
mean as much to me as a bible to a preacher. Electrolytic Tin
Electrolytic tin is used in the manufacture of dairy
equipment, coffee urns, condensers, wash boilers, etc. I doubt if this
subject would
be of much interest, as very few of the platers do any tin plating.
The
solution we use is our own patented acid solution which is very costly
to make and requires the porous cell method of obtaining metallic
content.
This would be out of the question for the average electroplater.
I recommend
the alkali tinning solution and preferably the stannate solution as
was thoroughly outlined by Mr. Proctor and published in
the last April
issue of the monthly review. You will get as good plating results
from it. It is a less costly solution, has cleaning properties which
the
acid does not have, and is easily controlled.
Tin plating requires strong
cleaning solutions and preferably an acid dip before tinning, providing
the work is not thoroughly buffed before
plating.
If, however, the work is buffed before plating, weaker cleaning solutions
will give better results and the acid dip can be eliminated.
Contrary
to the general opinion, defects in polished work before tinning show
up again when the tin is polished, as does nickel and chromium.
Better plating is obtained by using the lower current densities rather
than the
higher ones.
Tin shows a wonderful deposit much better than that produced
by the molten method. Any thickness can be deposited, perfectly uniform.
We
are also going to install a lead plating unit, but at the present time
have only done experimenting on it. W. S. Ermlich.
A. E. S. PAGE
Assembled Expert Scraps With and Without Significance
‘MEMBER
BACK WHEN?
You put out a bucket of water for the iceman to wash
off the sawdust before putting the ice in the box.
* * *
Our weekly allowance was a quarter, and we paid for our tablets and
pencils from this sum, and even managed to save enough for an occasional
gift
to ”Pa” and ”Ma.”
* * *
Bicycles were considered a menace to pedestrian safety and some towns
provided bicycle paths, the users of which had license tags on their ”wheels.”
*
* *
We men wore detachable cuffs, with cuff holders fastened to our shirts.
*
* *
The Twentieth Century Girl
Blessings on thee, little dame,
Bareback girl, with knees the same;
With thy rolled down, silken hose,
And thy short, transparent clothes;
With thy red lips, redding—
With the lipstick from the store;
I wish you all the luck and joy,
Glad that I was born a boy. —R. Dick.
* * *
Summary of Events in Trumbour Family
1913—Thos. Trumbour, Capt. East Baseball Team.
1928—Daughter Joan, flying over Detroit.
1930—Grand-dad.
Not much more baseball, Tom.—Editor.
* * *
Street cars in small towns carried a mail box and the motorman would
stop the car when any one wanted to mail a letter.
* * *
Ladies removed all hairpins from their hair during an electrical storm.
*
* *
The whole family ate breakfast at the same time.
* * *
People ate all they wanted and never heard of dieting.
* * *
A Calamity
American (at Scottish football
game): ”Why don’t
they start ? They ought to have kicked off an hour ago.”
Scotchman: ”Aye, something serious has happened.”
American: ”Not a player taken off ill ?”
Scotchman: ”No, worse than that, they canna find the penny they tossed
up with.” —Jos. Vilet.
|