Hard Chrome Plating Training Course
Contributing Authors
Larry Zitko, ChromeTech
George Cushnie, NMFRC
Paul Chalmer
Randy Taylor, Advanced Tooling Corp.
Table of Contents
Section 1: Course Overview
Section 2: Introduction To Hard Chrome Plating
What is Hard Chrome Plating?
Hard Chrome vs. Decorative Chrome
Why We Use Hard Chrome
Hardness
Abrasion Resistance
Low Coefficient of Friction
Good Adhesion
High Oil Retention
High Melting Point
Thermal Conductivity
Lubricity
Corrosion Resistance
Section 2 Quiz
Section 3: Process Chemistry And Equipment
Chromium—Chemical Terminology
Types of Plating Baths in Common Use
Conventional, Single-Catalyst Bath
Fluoride, Mixed-Catalyst Bath
High-speedn Non-etch, Proprietary Bath
Electricity and Hard Chrome Plating
Power Supplies Used for Hard Chrome Plating Systems
Factors in Choosing a Power Supply for Hard Chrome Plating 9
Air Cooling vs. Wate Cooling for Power Supplies
Rectifier Bussing and Tank Bus Bars
3 Bus Bar Design
2 Bus Bar Design
Tanks
Chrome Plating Tanks
Environmental Releases of Chromium from Plating Tanks
Alkaline Electrostrip Tanks
Scrub/Clean/Electroclean Tanks
Rinse Tanks
Anodes
Solution Heating
Solution Cooling
Solution Agitation
Exhaust Ventilation and Air Pollution Control
Encapsulating Hood
Exhaust Fans
Environmental Releases of Chromium to Air
Air Pollution Control
Section 3 Quiz
Section 4: Plating Procedures
Preplate Analysis
Stress Relief Bake
Shot Peen
Pre-cleaning
Masking
Racking/Fixturing
Cleaning
Water Break Test
Activation/Etch
Chrome Plating
Amps vs.Volts
Rinsing
Hydrogen Embrittlement Relief
Chromium Stripping
Plating on Special Base Metal
Section 4 Quiz
Section 5: Troubleshooting
Poor Chrome Appearance
Poor or Partial Coverage
Anode Placement and Size
Poor Throwing Power
Trees
Poor Adhesion
Roughness
Pitting
Arcing
Poor Corrosion Resistance
Micro-Cracking
Macro (Mud) Cracking
Slow Plating Rates
Uneven Chromium Deposition
Wild Chrome
Section 5 Quiz
Section 6: Plating Bath Impurities And Treatment Technologies
Analytical Data
Preventing Contamination and Removing Contaminants
Trivalent Chromium (Cr+3 )
Metallic Impurities - Tramp Metals
Metallic Impurity Limits
Dummy Plating
Ion Transfer - Porous Pot
Ion Transfer - Membrane Type
Advanced Membrane Technologies
Ion Exchange
Chloride
Suspended Solids
Oil and Grease
Section 6 Quiz
Section 7: Health And Safety
Health Risks Associated with Exposure to Hexavalent Chromium
Skin Contact
Ingestion
Breathing
Additional Safety Measures
Protect Yourself in Case of an Accident
Section 7 Quiz
Section 8: Pollution Prevention
What is Pollution Prevention (P2)?
Benefits of P2
P2 in Action
Rinse Water P2 Techniques
Rinsing
What is Hazardous Waste?
Prevent Bath Contamination
Air Emissions
P2 Implementation
P2 Summary
Section 8 Quiz
Appendix 1: Answers to Quizzes
Appendix 2: Acronyms and Abbreviations
Appendix 3: Reverse Etch Times
Appendix 4: Calculation of Surface Area
Appendix 5: Plating Parts Using a Plating Log
Appendix 6: Amps vs.Volts
Appendix 7: Troubleshooting Summary
Appendix 8: Conversion of Degrees Baumé to Concentrate for Chromic Acid
Appendix 9: Tracking Down Voltage Drops
Appendix 10: Conversion of Units
Appendix 11: Glossary